An extremely high-efficiency solution-processed white organic light-emitting diode (WOLED) is successfully developed by simultaneously using an ideal dendritic host material and a novel efficient orange phosphorescent iridium complex. The optimized device exhibits forward-viewing efficiencies of 70.6 cd A(-1) , 26.0%, and 47.6 lm W(-1) at a luminance of 100 cd m(-2) , respectively, promising the low-cost solution-processed WOLEDs a bright future as the next generation of illumination sources.
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http://dx.doi.org/10.1002/adma.201104758 | DOI Listing |
Huan Jing Ke Xue
January 2025
Department of Life Sciences, Changzhi University, Changzhi 046011, China.
The potential threat of soil microplastics (MPs, particle sizes smaller than 5 mm) to the agricultural environment and food security production has become a hot issue, but there are few systematic studies on the characteristics and influencing factors of MP pollution in agricultural soil in China. Based on the data of soil MPs and related environmental factors (temperature, precipitation, soil pH, and organic carbon) and social and economic factors (permanent population, gross regional product per capita, gross industrial product per capita, and cultivated land area per capita) extracted from 6 694 samples from 85 published studies from 2020 to 2023, meta-analysis was performed. The characteristics of MPs pollution in agricultural soil and the key factors affecting the accumulation of MPs in soil in six administrative regions of China were analyzed.
View Article and Find Full Text PDFChem Asian J
December 2024
University of Oklahoma, Chemistry and Biochemistry, 101 Stephenson Pkwy, Room 3310, 73019, Norman, UNITED STATES OF AMERICA.
Proton-coupled electron transfer (PCET) reactions are fundamental to energy storage and conversion processes. By coupling electrons with protons, the net charge neutrality is retained, preventing electrode decomposition due to charge imbalance. PCET reactions with equimolar amounts of protons and electrons can be considered as a net H-atom transfer (HAT) reaction.
View Article and Find Full Text PDFChemistry
December 2024
Universitat Duisburg-Essen, Institute of organic chemistry, Universitätsstraße 7, 45117, Essen, GERMANY.
In recent years, researchers studying fluorogenic samples have steadily shifted from using large, expensive, poorly soluble fluorophores with complex synthetic sequences to smaller, simpler p scaffolds with low molecular weight. This research article presents an in-depth study of the photophysical properties of five bridged single-benzene-based fluorophores (SBBFs) investigated for their solution and solid-state emission (SSSE) properties. The compounds O4, N1O3, N2O2, N3O1, and N4 are derived from a central terephthalonitrile core and vary in the amount of oxygen and nitrogen bridging atoms.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
South China University of Technology School of Materials Science and Engineering, State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, 381 Wushan Road, 510640, Guangzhou, CHINA.
The exploration of circularly polarized luminescence is important for advancing display and lighting technologies. Herein, by utilizing isomeric molecular engineering, a novel series of chiral molecules are designed to exploit both thermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP) mechanisms for efficient luminescence. The cooperation of a small singlet-triplet energy gap, moderate spin-orbital coupling (SOC), and large oscillator strength enables efficient TADF emission, with photoluminescence quantum yields exceeding 90%.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Universitat Jaume I - Campus de Riu Sec, Inorganic and Organic Chemistry, SPAIN.
This study introduces a novel and sustainable approach using Ionic Liquids (ILs) as a non-innocent solvent that enhances the performance of the basic catalysts to depolymerize polyurethane foam wastes (PUFWs) through hydrolysis, alcoholysis or aminolysis under mild conditions. The system is stable, fully recoverable, and reusable. Hydrolysis of PUFWs can occur in just 2 minutes at 95-98 °C, producing a white polyol that is easily separated and reused in new polyurethane synthesis.
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