Plasma optical spectroscopy is widely employed in on-line welding diagnostics. The determination of the plasma electron temperature, which is typically selected as the output monitoring parameter, implies the identification of the atomic emission lines. As a consequence, additional processing stages are required with a direct impact on the real time performance of the technique. The line-to-continuum method is a feasible alternative spectroscopic approach and it is particularly interesting in terms of its computational efficiency. However, the monitoring signal highly depends on the chosen emission line. In this paper, a feature selection methodology is proposed to solve the uncertainty regarding the selection of the optimum spectral band, which allows the employment of the line-to-continuum method for on-line welding diagnostics. Field test results have been conducted to demonstrate the feasibility of the solution.
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http://dx.doi.org/10.3390/s91007753 | DOI Listing |
RSC Adv
December 2018
Institute of Fluid Physics, China Academy of Engineering Physics Mianyang Sichuan 621900 P. R. China
A method that can reutilize the energy of a nanosecond pulse laser beam and its performance in single particle triggered laser induced breakdown spectroscopy (LIBS) were studied. The propagation direction of the laser beam (Nd-YAG laser, 1064 nm, 9 ns and 0-80 mJ) was changed in an appropriate way and the energy overlapped at one point in space. In this setup, the energy used to break down pure air was reduced by 25% and the emission intensity of air plasma improved by 220% under the same pulse energy.
View Article and Find Full Text PDFMicroplasma is generated in an ultra-high-pure H and N gas mixture with a Nd:YAG laser device that is operated at the fundamental wavelength of 1064 nm. The gas mixture ratio of H and N is 9 to 1 at a pressure of 1.21 ± 0.
View Article and Find Full Text PDFThe electron temperature was evaluated using the line-to-continuum ratio method, and whether the plasma was close to the local thermodynamic equilibrium (LTE) state was investigated in detail. The results showed that approximately 5 μs after the plasma formed, the changes in the electron and excitation temperatures, which were determined using a Boltzmann plot, overlapped in the 15% error range, which indicated that the LTE state was reached. The recombination of electrons and ions and the free electron expansion process led to the deviation from the LTE state.
View Article and Find Full Text PDFIn this paper, the effect of laser pulse energy on orthogonal double femtosecond pulse laser induced breakdown spectroscopy (LIBS) in air is studied. In the experiment, the energy of the probe pulse is changeable, while the pump pulse energy is held constant. At the same time, a systematic study of the laser induced breakdown spectroscopy signal dependence on the inter-pulse delay between the two pulses is performed.
View Article and Find Full Text PDFAnal Chem
July 2012
Marine Biodiscovery Centre (MBC), Chemistry, University of Aberdeen, Aberdeen, Scotland, UK.
Driven by increasing demand for the monitoring of industrial perfluorinated compounds (PFCs), the identification of novel fluorine containing compounds (FOCs) and the tracking of organofluorine drugs and their degradation products, there is a clear need for sensitive, fluorine-specific detection of unknown FOCs. Here we report the first ever direct fluorine-specific (speciation) method; capable of individually detecting untargeted FOCs in environmental and biological samples through the application of continuum source molecular absorption spectrometry (CS-MAS) using a commercial CS-AAS. Two model FOCs (2,4,6, trifluorobenzoic acid (TFBA) and 5-fluoroindol-5-carboxylic acid (FICA)) were used, achieving fluorine-specific detection across a range of 0.
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