The cross-coupling reaction of aryltrimethylammonium iodides with aryl- or heteroarylzinc chlorides catalyzed by amido pincer nickel complexes was performed. The reaction requires low catalyst loading and displays broad substrate scope.
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http://dx.doi.org/10.1021/jo300209d | DOI Listing |
Chem Asian J
December 2017
CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Reaction of aryltrimethylammonium iodides with arylzinc chlorides in the absence of a transition-metal catalyst to form biaryl compounds was performed under mild conditions. The reaction was suitable for a broad scope of substrates and exhibited good compatibility of functional groups. The Mg ion was demonstrated to markedly promote the reaction.
View Article and Find Full Text PDFJ Org Chem
April 2012
CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
The cross-coupling reaction of aryltrimethylammonium iodides with aryl- or heteroarylzinc chlorides catalyzed by amido pincer nickel complexes was performed. The reaction requires low catalyst loading and displays broad substrate scope.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
May 2011
CAS Key Laboratory of Soft Matter Chemistry, Joint laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
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