The notion that decoherence rapidly reduces a superposition state to an incoherent mixture implicitly adopts a special representation, namely, the representation of preferred (pointer) states (PS). For weak or strong system-envrionment interaction, the behavior of PS is well known. Via a simple dynamical model that simulates a two-level system interacting with few other degrees of freedom as its environment, it is shown that even for intermediate system-environment coupling, approximate PS may still emerge from the coherent quantum dynamics of the whole system in the absence of any thermal averaging. The found PS can also continuously deform to expected limits for weak or strong system-environment coupling. Computational results are also qualitatively explained. The findings should be useful towards further understanding of decoherence and quantum thermalization processes.
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http://dx.doi.org/10.1103/PhysRevLett.108.070403 | DOI Listing |
J Chem Phys
January 2025
Department of Physics, University of Pretoria, 0002 Pretoria, South Africa.
Much can be learned about molecular aggregates by modeling their fluorescence-type spectra. In this study, we systematically describe the accuracy of various methods for simulating fluorescence-type linear spectra in a dimer system with a complex system-environment interaction, which serves as a model for various molecular aggregates, including most photosynthetic light-harvesting complexes (LHCs). We consider the approximate full cumulant expansion (FCE), complex time-dependent Redfield (ctR), time-independent Redfield, and modified Redfield methods and calculate their accuracy as a function of the site energy gap and coupling, excitonic energy gap, and dipole factor (i.
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Institute for Quantum Computing, University of Waterloo, Waterloo, ON, Canada.
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View Article and Find Full Text PDFGround Water
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Seafloor Science Branch, US Naval Research Laboratory, NRL Code 7432, Stennis Space Center, Hancock County, MS, 39529.
Our recent steady-state mass-balance modeling suggests that most global carbonic-acid weathering of silicate rocks occurs in the vadose zone of aquifer systems not on the surface by atmospheric CO. That is, the weathering solute flux is nearly equal to the total global continental riverine carbon flux, signifying little atmospheric weathering by carbonic acid. This finding challenges previous carbon models that utilize silicate weathering as a control of atmospheric CO levels.
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November 2024
Optics and Quantum Information Group, The Institute of Mathematical Sciences, C.I.T. Campus, Taramani, Chennai 600113, India.
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