AI Article Synopsis
- This study explores the formation of Ln(III) complexes using a ditopic ligand called L1, focusing on their structural, thermodynamic, and photophysical characteristics.
- Spectrophotometric and NMR titrations reveal the creation of triangular assemblies, denoted as [Ln(3)(L1-H)(3)](6+), which are compared to similar complexes containing a different ligand, L2.
- The research also identifies a dinuclear species, [Ln(2)(L1-H)](5+), when there is a surplus of metal present in the mixture.
Article Abstract
This contribution investigates Ln(III) complexes formed with a small ditopic ligand, L1, and their structural, thermodynamic and photophysical properties. The spectrophotometric and NMR titrations evidence the triangular assemblies [Ln(3)(L1-H)(3)](6+) at stoichiometric conditions and their properties are discussed in relation to L2-containing analogues. In addition, the dinuclear species, [Ln(2)(L1-H)](5+), is observed with an excess of metal.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2dt12227h | DOI Listing |
Publication Analysis
Top Keywords
lanthanide-mediated triangular
4
triangular cationic
4
cationic assemblies
4
assemblies structural
4
structural physico-chemical
4
physico-chemical properties
4
properties contribution
4
contribution investigates
4
investigates lniii
4
lniii complexes
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!