AI Article Synopsis
- - The bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) interacts with L(2)M(CO)(4) complexes (where M can be molybdenum or tungsten) to form bidentate complexes.
- - These bidentate complexes exhibit an unusual coordination pattern, including the involvement of the Ge(II) center and a single phosphorus atom.
- - Additionally, interactions with AuI or Me(2)SAuCl result in monodentate complexes that are coordinated solely at the germanium(II) atom.
Article Abstract
The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.
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| http://dx.doi.org/10.1039/c2cc17551g | DOI Listing |
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