Modified rheokinetic technique to enhance the understanding of microcapsule-based self-healing polymers.

A modified rheokinetic technique was developed to monitor the polymerization of healing monomers in a microcapsule-based, self-healing mimicking environment. Using this modified technique, monomers active toward ring-opening metathesis polymerization (ROMP) were either identified or disregarded as candidates for incorporation in self-healing polymers. The effect of initiator loading on the quality and speed of healing was also studied. It was observed that self-healing polymers have upper and lower temperature limits between which the healing mechanism performs at optimal levels. Also, a study of the quality of healing cracks of different thicknesses was performed, and it was discovered that above a critical crack thickness value, the quality of self-healing diminishes substantially; reasons for this phenomenon are discussed in detail.