In this work, we coupled synchrotron vacuum ultraviolet photoionization (SVUV PI) method with the laser-induced acoustic desorption (LIAD) technique for mass spectrometric analysis. The LIAD technique is a "soft" desorption method, which could avoid the degradation of analytes during desorption process. Meanwhile, SVUV PI is an efficient "soft" ionization source. The new combination of the "soft" desorption technique and "soft" photoionization method is well suitable to reduce the difficulty for interpreting the mass spectra of the fragile compounds and heavy oils.
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http://dx.doi.org/10.1063/1.3685251 | DOI Listing |
Nano Lett
December 2024
Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin, 13083-859 Campinas, Brazil.
The interaction of high-frequency surface acoustic waves (SAWs) and excitons in van der Waals heterostructures (vdWHs) offers challenging opportunities to explore novel quantum effects and functionalities. We probe the interaction of neutral excitons, trions, and biexcitons with SAWs in a hBN/WSe/hBN vdWH. We show that neutral excitons respond weakly to the SAW stimulus at 5 K.
View Article and Find Full Text PDFStruct Dyn
November 2024
Department of Physics and Astronomy, Uppsala University, Box 516, 75120 Uppsala, Sweden.
Light-matter interaction at the nanoscale in magnetic alloys and heterostructures is a topic of intense research in view of potential applications in high-density magnetic recording. While the element-specific dynamics of electron spins is directly accessible to resonant x-ray pulses with femtosecond time structure, the possible element-specific atomic motion remains largely unexplored. We use ultrafast electron diffraction (UED) to probe the temporal evolution of lattice Bragg peaks of FePt nanoparticles embedded in a carbon matrix following excitation by an optical femtosecond laser pulse.
View Article and Find Full Text PDFJ Mech Behav Biomed Mater
December 2024
Department of Mechanical Engineering, University of Michigan, Ann Arbor, MI, USA. Electronic address:
Perfluorocarbon (PFC) droplets represent a novel class of phase-shift contrast agent with promise in applications in biomedical and bioengineering fields. PFC droplets undergo a fast liquid-gas transition upon exposure to acoustic or optical triggering, offering a potential adaptable and versatile tool as contrast agent in diagnostic imaging and localized drug delivery vehicles in therapeutics systems. In this paper, we utilize advanced imaging techniques to investigate ultra-high-speed inertial dynamics and rectified quasi-static (low-speed) diffusion evolution of optically induced PFC droplet vaporization within three different hydrogels, each of different concentrations, examining effects such as droplet size and PFC core on bubble dynamics and material viscoelastic properties.
View Article and Find Full Text PDFAnal Chem
October 2024
UMALaserLab, Departamento de Química Analítica, Universidad de Málaga, Jiménez Fraud 4, Málaga 29010, España.
The process of laser-induced breakdown of amorphous and crystalline selenium nanoparticles (Se NPs) of various shapes during nanosecond laser fragmentation of aqueous colloidal solutions of nanoparticles with different concentrations has been studied. The methods of studying the characteristics of plasma and acoustic oscillations induced by optical breakdown are applied. The methods of assessing the concentration of hydrogen peroxide and hydroxyl radicals, the amount of long-lived reactive species of protein and 8-oxoguanine are applied.
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