Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds.

Dalton Trans

Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, P. O. Box 55, FIN-00014, Finland.

Published: April 2012

Aromatic carbonyl compounds in combination with B(C(6)F(5))(3) are able to activate H(2) heterolytically. The reactivity of the carbonyl-B(C(6)F(5))(3) adduct is initiated by its thermal dissociation into components. After H(2) addition, aromatic carbonyl compounds convert into aryl-substituted methanes or alcohols.

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Source
http://dx.doi.org/10.1039/c2dt12268eDOI Listing

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