The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2cc17915f | DOI Listing |
Publication Analysis
Top Keywords
total synthesis
8
synthesis +-mucosin
8
+-mucosin total
4
+-mucosin completed
4
completed allowing
4
allowing assignment
4
assignment absolute
4
absolute stereochemistry
4
stereochemistry natural
4
natural product
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!