The title compound, C(9)H(11)NO(2), was obtained as an unexpected product in an attempt to synthesize a triazene ligand. The title mol-ecule is almost planar, with the formamide and eth-oxy groups oriented at 2.7 (3) and 12.9 (2)°, respectively, with respect to the mean plane of the benzene ring. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming a chain along the a axis. Weak C-H⋯π inter-actions with an H⋯π distance of 2.78 Å reinforce the crystal packing, resulting in a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275250PMC
http://dx.doi.org/10.1107/S160053681200205XDOI Listing

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