In the title homochiral mononuclear compound, [Zn(NO(3))(2)(C(6)H(12)N(4)O(2))(2)], the Zn(II) atom is located on a twofold rotation axis and coordinated by two N atoms from two ligands and two O atoms from two NO(3) (-) anions, adopting a distorted tetra-hedral coordination geometry. The compound is enanti-omerically pure and corresponds to the S diastereoisomer, with the optical activity originating from the chiral ligand. In the crystal, mol-ecules are connected into three-dimensional supra-molecular networks through O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274914 | PMC |
| http://dx.doi.org/10.1107/S1600536812001754 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
-Bis(quinoline-8-amine-κ ,')bis-(1,1,3,3-tetra-cyano-2-meth-oxy-propenido-κ)iron(II).
IUCrdata
December 2024
The title compound, [Fe(CHNO)(CHN)], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Fe ion is located on an inversion centre.
View Article and Find Full Text PDFCrystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis-(2-iodoethyl-ammonium) [di-μ-iodido-di-iodido-germanate(II)]].
Acta Crystallogr E Crystallogr Commun
January 2025
Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine.
The title compound is a germanium-based hybrid metal halide that represents a less-toxic alternative to more popular lead-based analogues in optoelectronic applications. {(2-ICHNH)[GeI]} is composed of infinite inorganic layers that are formed by [GeI] octa-hedra connected in a corner-sharing manner with four equatorial I atoms. The organic (2-ICHNH) cations inter-leave the inorganic layers.
View Article and Find Full Text PDFSynthesis, crystal structure and Hirshfeld surface analysis of bis-(acetyl-acetonato-κ ,')(2-amino-1-methyl-1-benzimidazole-κ )copper(II).
Acta Crystallogr E Crystallogr Commun
January 2025
The title compound, [Cu(CHO)(CHN)], crystallizes in the ortho-rhom-bic space group . In the crystal structure, the Cu ion is coordinated by two acetyl-acetonate ligands and one 2-amino-1-methyl-1-benzimidazole ligand. The crystal structure features intra-molecular N-H⋯O and inter-molecular N-H⋯O hydrogen bonds, which contribute to the overall cohesion of the crystal.
View Article and Find Full Text PDFCrystal structure of -poly[bis-(,-di-methyl-hydroxyl-ammonium) [di-μ-bromido-di-bromido-stannate(II)]].
Acta Crystallogr E Crystallogr Commun
January 2025
Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska str. 64/13, 01601 Kyiv, Ukraine.
The title compound, {(CHNO)[SnBr]} , is a layered hybrid perovskite crystallizing in the monoclinic space group 2/. The asymmetric unit consists of one HC-O-NH -CH cation (MeHA), one Sn atom located on a twofold rotation axis, and two Br atoms. The Sn atom has a distorted octa-hedral coordination environment formed by the bromido ligands.
View Article and Find Full Text PDFSynthesis and crystal structure of -10-(4-cyano-phen-yl)-10,11,22,23-tetra-hydro-9,21-5,8:15,12-bis-(metheno)[1,5,11]tri-aza-cyclo-hexadecino[1,16-:5,6-']di-indole di-chloro-methane monosolvate.
Acta Crystallogr E Crystallogr Commun
January 2025
Osaka Research Institute of Industrial Science and Technology, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan.
The asymmetric unit of the title compound is composed of one host mol-ecule, -4-(1 ,5 -3-aza-1,5(3,9)-dicarbazola-cyclo-octa-phane-3-yl)benzo-nitrile and one di-chloro-methane solvate mol-ecule, CHN·CHCl. The host mol-ecule possesses a planar chirality but crystallizes as a racemate in the space group 2/. It adopts an -configuration, in which two carbazole rings are partially overlapped with a parallel orientation.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!