Bis(2-amino-1,3-benzothia-zole-κN)dichloridozinc(II) ethanol hemisolvate.

Acta Crystallogr Sect E Struct Rep Online

Published: February 2012

In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-amino-benzothia-zole ligands and two Cl atoms within a distorted tetra-hedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothia-zole mol-ecules are almost perpendicular to each other, forming a dihedral angle of 80.20 (8)°. The mol-ecular structure is stabilized by intra-molecular N-H⋯Cl hydrogen bonds. In the crystal, inter-molecular N-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional network. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155] was used to model a disordered ethanol solvent mol-ecule; the calculated unit-cell data allow for the presence of half of this mol-ecule in the asymmetric unit.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274905PMC
http://dx.doi.org/10.1107/S1600536812001560DOI Listing

Publication Analysis

Top Keywords

dihedral angle
8
n-h⋯cl hydrogen
8
hydrogen bonds
8
bis2-amino-13-benzothia-zole-κndichloridozincii ethanol
4
ethanol hemisolvate
4
hemisolvate title
4
title compound
4
compound [zncl2c7h6n2s2]·05ch3ch2oh
4
[zncl2c7h6n2s2]·05ch3ch2oh znii
4
znii atom
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!