A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

catena-Poly[[(5-phenyl-2,2'-bipyridine-κN,N')copper(I)]-μ-thio-cyanido-κN:S]. | LitMetric

The title compound, [Cu(NCS)(C(16)H(12)N(2))](n), was synthesised under hydro-thermal conditions. The Cu(I) ion shows distorted tetra-hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2'-bipyridine ligand and by the N and S atoms from two different thio-cyanate anions. The Cu(I) ions are bridged by thio-cyanide groups, forming a one-dimensional coordination polymer along the b axis. The crystal packing is through van der Waals contacts and C-H⋯π inter-actions.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274895PMC
http://dx.doi.org/10.1107/S1600536812000682DOI Listing

Publication Analysis

Top Keywords

catena-poly[[5-phenyl-22'-bipyridine-κnn'copperi]-μ-thio-cyanido-κns] title
4
title compound
4
compound [cuncsc16h12n2]n
4
[cuncsc16h12n2]n synthesised
4
synthesised hydro-thermal
4
hydro-thermal conditions
4
conditions cui
4
cui ion
4
ion distorted
4
distorted tetra-hedral
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!