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Diaqua-bis-(N,N-diethyl-pyridine-3-carboxamide-κN)bis-{4-[2-(2,4-dioxopentan-3-yl-idene)hydrazin-1-yl]benzoato-κO}copper(II). | LitMetric

In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl-ate O atoms, pyridine N atoms and two water mol-ecules in an elongated octa-hedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intra-molecular O-H⋯O and N-H⋯O hydrogen bonding is observed. The water mol-ecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxyl-ate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274866PMC
http://dx.doi.org/10.1107/S1600536811056200DOI Listing

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