The study is focused on the external and internal mass transfers of lipids during their biodegradation process in a bioreactor with stationary basket bed of immobilized Bacillus spp. cells. By means of the lipid mass balance for a single particle of biocatalyst, considering the kinetic model adapted for the immobilized bacterial cells, specific mathematical models have been developed to estimate their mass flows in the liquid boundary layer surrounding the particle and inside the particle. The values of mass flows are significantly influenced by the internal diffusion velocity of lipids and the rate of their consumption, but also by the position inside the basket bed. These influences accumulated led to the appearance of a biological inactive region near the particle centre, its magnitude varying from 1.3 to 49.4% of the overall volume of particles.
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http://dx.doi.org/10.2166/wst.2012.938 | DOI Listing |
Bioresour Technol
December 2024
Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland; Biotechnology Center, Silesian University of Technology, Krzywoustego 8, 44-100 Gliwice, Poland. Electronic address:
Biomass pretreatment and conversion are crucial for sustainable development, but lack information on equipment that ensures effective mass transfer and easy biomass separation post-process. This work introduces a novel basket reactor with a stationary bed (StatBioChem) for biomass processing using deep eutectic solvents (DESs). We compared the delignification efficiencies of soft and hard biomass samples processed in the StatBioChem reactor, a stirred tank reactor (STR), and a commercial SpinChem® reactor.
View Article and Find Full Text PDFHeterogeneity is the concept we encounter in numerous research areas and everyday life. While "not mixing apples and oranges" is easy to grasp, a more quantitative approach to such segregation is not always readily available. Consider the problem from a different angle: To what extent does one have to make apples more orange and oranges more "apple-shaped" to put them into the same basket (according to their appearance alone)? This question highlights the central problem of the blurred interface between heterogeneous and homogeneous, which also depends on the metrics used for its identification.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2023
Department of Africa, Trade Promotion Organization of Iran, Tehran, Iran.
Diversification of energy mix is related to the heterogeneity of contributions of energy sources in the energy consumption basket of nations. Its persistent degree reveals the efficiency of energy-related policies or shocks to diversify the contributions of energy sources in the energy mix. For the first time, the current study measures the diversification level of energy mix of the USA and its 51 states and examines its stochastic behavior to analyze its degree of persistence.
View Article and Find Full Text PDFMaterials (Basel)
June 2023
Department of Production Engineering, Faculty of Mechanical Engineering, Koszalin University of Technology, Racławicka 15-17, 75-620 Koszalin, Poland.
The article concerns the application of the FEM method for the prediction of stress and deformation states in a workpiece during the thread rolling process (TR). The analysis covered a new kinematic variant of the TR process in which the basket of the head rotates and is torque-driven, while the workpiece is stationary and the head with the rollers moves axially relative to the workpiece. The TR process was considered as a geometrical and physical non-linear initial and boundary problem with non-linear, moving, and variable in time and space boundary conditions.
View Article and Find Full Text PDFJ Chromatogr A
August 2023
Department of Chemistry and Biotechnology, Perm National Research Polytechnic University, 29 Komsomolsky Al, Perm 614990, Russia.
Retention and separation of enantiomers of amine derivatives of indane and tetralin (rasagiline and its analogues) on chiral stationary phases (CSPs) Chiral-T and Chiral-V with teicoplanin and vancomycin antibiotics grafted onto superficially porous silica particles under conditions of reversed-phase and polar organic chromatography were studied. The mobile phases (MP) were water-methanol and acetonitrile-methanol solvents modified with triethylamine-acetic acid buffer. The effects of molecular structure and physical properties of the analytes on enantioselective retention are discussed.
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