An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.
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January 2025
Anhui Provincial Key Laboratory of Advanced Catalysis and Energy Materials, Anhui Ultra High Molecular Weight Polyethylene Fiber Engineering Research Center, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246133, P. R. China.
The catalytic conversion of CO into valuable chemicals using metalized covalent organic frameworks (COFs) as catalysts is a promising method for reducing atmospheric CO levels. Herein, a aldehyde-amine COF (TAPT-Tp) at room temperature and pressure and their metallized results is synthesized, Ni-TAPT-Tp and Ti-TAPT-Tp. The photocatalytic results indicate that the CO to CO reduction rate is 6182.
View Article and Find Full Text PDFUndersea Hyperb Med
January 2025
Hansjorg Wyss Department of Plastic Surgery, NYU Grossman School of Medicine, New York, NY.
Introduction: When administering HBO , pressures can range from 1.4 atmospheres absolute (ATA) to 3 ATA. While different treatment profiles have been proposed, there is a paucity of literature comparing the effectiveness and risk profile associated with different pressures treating the same condition.
View Article and Find Full Text PDFUndersea Hyperb Med
January 2025
Graduate Program in Veterinary Medicine, Center of Rural Science, Federal University of Santa Maria (UFSM), Av. Roraima, 1000, building 42, room 3135, 97105-900 Santa Maria, RS, Brazil.
The assessment of rectal temperature and behavior is an important parameter in all patients for whom hyperbaric oxygen (HBO) therapy is used. The study aims to verify if there is less reduction in body temperature after HBO therapy in restless patients and their behavior during the therapeutic session. Clinical data from 217 HBO therapy sessions with 2 to 2,5 atmospheres absolute (ATA) were reviewed under therapy protocols of 30 (P1) or 45 (P2) minutes, covering 29 canines and 13 felines.
View Article and Find Full Text PDFChempluschem
January 2025
L V Pisarzhevskii Institute of Physical Chemistry NAS of Ukraine: Institut fiziceskoj himii imeni L V Pisarzevskogo Nacional'na akademia nauk Ukraini, Department of free radicals, UKRAINE.
This study unveils a novel property of polyaniline by establishing its catalytic activity in heterogeneous hydrogenation with molecular hydrogen. Polyaniline was activated by heat-treating at different temperatures in a hydrogen atmosphere. The sample treated at 300 °C exhibited the highest catalytic activity for ethylene hydrogenation in the gas phase at atmospheric pressure and for p-nitrotoluene or α-methylstyrene hydrogenation in the liquid phase.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Mechanical Engineering, Tarbiat Modares University, Tehran, Iran.
In this study, a series of experiments are done to analyze the effect of bluff body geometry on the NO reduction of a natural gas-air stratified swirl burner. The stratified burner of Cambridge University is chosen to study the mentioned geometrical effect, and the geometry modification of bluff body is used as a simple method for NO reduction, which can be easily applied to the systems using these burners, including gas turbines. The bluff body geometrical change to an annular bluff body is inspired by the fact that the areas in which the edge of the bluff body is in contact with the unburned flow have lower temperatures, which can drastically affect combustion parameters, especially emissions.
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