Graphite is exfoliated into graphene by shearing vortex fluidic films of N-methyl-pyrrolidone (NMP), as a controlled process for preparing oxide free graphene, and for exfoliating the corresponding boron nitride sheets.
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http://dx.doi.org/10.1039/c2cc17611d | DOI Listing |
ChemSusChem
January 2025
Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan, QLD, 4111, Australia.
Carbon dots (CDs) as a new class of photoluminescent zero-dimension carbon nanoparticles have attracted significant research interests owing to their extraordinary opto-electro-properties and biocompatibility. So far, almost all syntheses of CDs require either heat treatment or exertion of high energy fields. Herein, a scalable room-temperature vortex fluidic method is introduced to the CDs synthesis using the angled vortex fluidic device (VFD).
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December 2024
Department of Electrical and Computer Engineering, National University of Singapore, Kent Ridge, Singapore, Republic of Singapore.
The structural periodicity in photonic crystals guarantees the crystal's effective energy band structure, which is the fundamental cornerstone of topological and moiré physics. However, the shear modulus in most fluids is close to zero, which makes it challenging for fluids to maintain spatial periodicity akin to photonic crystals. We realized periodic vortices in hydrodynamic metamaterials and created a bilayer moiré superlattice by stacking and twisting two such vortex fluids.
View Article and Find Full Text PDFChemistry
November 2024
Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Adelaide, SA 5042, Australia.
We have developed a rapid and facile method for preparing free-standing nanocomposite of gold nanoparticles with graphene oxide (Au@GO) in water under continuous flow in the absence of harsh reducing agents and any other auxiliary substances, as a method with favourable green chemistry metrics. This uses a vortex fluidic device (VFD) where induced mechanical energy and photo-contact electrification associated with the dynamic thin film in the rapidly rotating tube tilted at 45° while simultaneously UV irradiated (λ=254 nm, 20 W) results in decomposition of water to hydrogen and hydrogen peroxide with growth of the gold nanoparticles on the surface of the GO. We have established that the resulting Au@GO composite sheets rapidly catalyse the degradation of commercial dyes like methyl orange (MO) and methylene blue (MB) using the hydrogen peroxide generated in situ in the VFD.
View Article and Find Full Text PDFMacromol Rapid Commun
November 2024
School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD, 4000, Australia.
Chemical reactions and transformations in non-traditional vessels have gained significant interest in recent years. Flow chemistry, with its advantages in mixing, mass transfer, scalability, and automation, is a driving force behind this paradigm shift. In particular, the Vortex Fluidic Device (VFD) has emerged as a versatile tool across various applications, from organic synthesis to materials science.
View Article and Find Full Text PDFCurr Protoc
September 2024
Department of Chemistry, University of California Irvine, Irvine, California.
This article details how to use a vortex fluidic device (VFD) to accelerate protein purification via immobilized metal affinity chromatography (IMAC). Building upon a previous report of VFD-based purification, we introduce a membrane insert to simplify the purification protocol and the resin recovery step. This new platform can be adapted to different types of IMAC resins and purification membranes.
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