The effect of hydrogen content on ballistic transport behaviors in the Ni-Nb-Zr-H glassy alloys.

Int J Mol Sci

Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan; E-Mail:

Published: February 2015

The electronic transport behaviors of (Ni(0.39)Nb(0.25)Zr(0.35))(100-) (x)H(x) (0 ≤ x < 23.5) glassy alloys with subnanostructural icosahedral Zr(5)Nb(5)Ni(3) clusters have been studied as a function of hydrogen content. These alloys show semiconducting, electric current-induced voltage (Coulomb) oscillation and ballistic transport behaviors. Coulomb oscillation and ballistic transport occur at hydrogen contents between 6.7 and 13.5 at% and between 13.5 and 21.2 at%, respectively. These results suggest that the localization effect of hydrogen in the clusters plays an important role in various electron transport phenomena.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3269680PMC
http://dx.doi.org/10.3390/ijms13010180DOI Listing

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