Chemistry, School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia M313, 35 Stirling Highway, Crawley, Western Australia 6009.
Published: March 2012
AI Article Synopsis
Article Abstract
Matrix isolation FTIR experiments have shown that methanol is a major product when argon gas doped with water and methane is exposed to an electrical discharge and condensed to a solid matrix at 11 K. Experiments with (2)H, (17)O and (18)O-labeled isotopologues show the mechanism for the methanol production is likely to be insertion of an excited oxygen atom in the (1)D state into a C-H bond of a methane molecule. In light of these experiments, the possibility of oxygen atom insertion into methane should be considered as a possible mechanism for the production of methanol in interstellar ices.
Aqueous Zn-S batteries provide competitive energy density for large-scale energy storage systems. However, the cathode active material exhibits poor electrical conductivity especially at the discharged state of ZnS. Its morphology generated in cells thus directly determines the cathode electrochemical activity.
State Key Laboratory of Silicate Materials for Architectures, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.
Polyvinylidene fluoride (PVDF) film, with high energy density and excellent mechanical properties, has drawn attention as an energy storage device. However, conduction loss in PVDF under high electric fields hinders improvement in efficiency due to electrode-limited and bulk-limited conduction. Well-aligned multilayer interfaces of two-dimensional (2D) nanocoatings can block charge injection, reducing electrode-limited conduction loss in dielectric polymers.
Energy conservation dictates that an electron with elementary charge e traversing a vacuum gap formed by electrodes maintained at potential difference U volts acquires maximum energy of eU. In many experiments electrons with energies as high as 3eU have been observed. The experimental discovery of this effect was made over 50 years ago and is still a subject of significant controversy in applications related to x-ray generation from high voltage discharges.
Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian 116024, People's Republic of China.
We present a novel resonance mode in capacitive radio frequency (rf) discharges in the presence of an oblique magnetic field at low pressures. We observe the self-excitation of high-frequency harmonics of the current in magnetized capacitive rf discharges through the magnetized plasma series resonance (MPSR) induced by applying a low-frequency power. Utilizing an equivalent circuit model, we reveal that these harmonics arise from the hybrid combination of the magnetic gyration of electrons and the PSR.
Multipactor, a vacuum discharge under microwave conditions triggered by secondary electron emission (SEE), plays a critical role in managing the power level of microwave devices. In this study, we developed a fluorocarbon-titanium composite film on aluminum by cosputtering polytetrafluoroethylene (PTFE) and titanium via a controlled temperature and sputtering power ratio (RF power for PTFE to DC power for Ti) to suppress the SEE of Al. The evolution of microtopography and chemical composition of the composite film was evaluated.
