Highly selective and sensitive colorimetric probe for hydrogen sulfide by a copper (II) complex of azo-dye based on chemosensing ensemble approach.

Spectrochim Acta A Mol Biomol Spectrosc

College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Songjiang, Shanghai, PR China.

Published: May 2012

A copper (II) complex of azo-dye (Cu-1) has been synthesized by the reaction of 1-(2-pyridylazo)-2-naphthol (1) with copper (II) chloride. The complex Cu-1 is able to selectively sense hydrogen sulfide over other anions followed by the release of compound 1 to give a remarkable change of UV-vis absorption at neutral pH in aqueous solution.

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http://dx.doi.org/10.1016/j.saa.2012.01.013DOI Listing

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