AI Article Synopsis
- A novel method has been created for making self-assembled conducting polymer films by applying increased centrifugal force during the electrochemical deposition process.
- Scanning electron microscopy demonstrated that higher g-forces led to a progression in polymer surface morphology from smooth to dense nanostructures with pores as small as 50 nm.
- Films produced under greater centrifugal acceleration (above 500g) showed improved durability and enhanced capacitive properties after electrochemical cycling.
Article Abstract
A simple, novel method of synthesizing self-assembled, nanostructured conducting polymer films has been developed. Applying an increased centrifugal force on the electrodes during the electrochemical deposition process yields high surface area, micro- or nanostructured polymer films. Scanning electron microscopy showed that as the applied g-force increased, the polymers progressed from having smooth, "cauliflower" morphologies, to intermediate microstructured surfaces, to finally dense nanostructured surfaces with pore sizes as small as 50 nm. Cyclic voltammetry revealed that films grown at higher centrifugal accelerations (higher than 500g) exhibited less degradation after electrochemical cycling and more capacitive behavior.
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| http://dx.doi.org/10.1021/la204605m | DOI Listing |
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