The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels-Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3272355 | PMC |
| http://dx.doi.org/10.1021/ol203355g | DOI Listing |
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