The mol-ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol-ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the mol-ecule. An intra-molecular O-H⋯N(imine) hydrogen bond is formed in each half of the mol-ecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N-H⋯O(hydrox-yl) hydrogen bonds in the crystal, which results in supra-molecular layers lying parallel to (100).

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530PMC
http://dx.doi.org/10.1107/S1600536811053268DOI Listing

Publication Analysis

Top Keywords

2-[e-2-{2-[e-2-hy-droxy-benzyl-idene]hydrazinecarbon-yl}hydrazinyl-idenemeth-yl]phenol mol-ecule
4
mol-ecule title
4
title compound
4
compound c15h14n4o3
4
c15h14n4o3 completed
4
completed application
4
application crystallographic
4
crystallographic twofold
4
twofold symmetry
4
symmetry carbonyl
4

Similar Publications

The mol-ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol-ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the mol-ecule.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!