catena-Poly[[bis-(acetato-κO)aqua-copper(II)]-μ-5-(pyridin-3-yl)pyrimidine-κN:N].

Acta Crystallogr Sect E Struct Rep Online

College of Pharmacy, Binzhou Medical University, Yantai 264003, People's Republic of China.

Published: January 2012

In the title compound, [Cu(CH(3)CO(2))(2)(C(9)H(7)N(3))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. The N atoms of the two chelating symmetry-related 5-(pyridin-3-yl)pyrimidine ligands and the O atoms of the two monodentate acetate anions are nearly coplanar, with a mean deviation from the least-squares plane of 0.157 (2) Å and the Cu(II) ion is displaced by 0.050 (3) Å from this plane towards the apical water O atom. Bridging through the bis-monodentate 5-(pyridin-3-yl)pyrimidine ligand forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional supra-molecular structure parallel to (100). The crystal studied was an inversion twin with a 0.57 (3):0.43 (3) domain ratio.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254350PMC
http://dx.doi.org/10.1107/S160053681105481XDOI Listing

Publication Analysis

Top Keywords

cuii ion
8
catena-poly[[bis-acetato-κoaqua-copperii]-μ-5-pyridin-3-ylpyrimidine-κnn] title
4
title compound
4
compound [cuch3co22c9h7n3h2o]n
4
[cuch3co22c9h7n3h2o]n cuii
4
ion penta-coordinated
4
penta-coordinated square-pyramidal
4
square-pyramidal geometry
4
geometry atoms
4
atoms chelating
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!