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http://dx.doi.org/10.1002/anie.201107144 | DOI Listing |
Entropy (Basel)
January 2025
Department of Information Systems, Chuvash State University, Moskovsky pr. 15, 428015 Cheboksary, Russia.
This paper focuses on differentiating between ideal and non-ideal chemical systems based on their kinetic behavior within a closed isothermal chemical environment. Non-ideality is examined using the non-ideal Marcelin-de Donde model. The analysis primarily addresses 'soft' non-ideality, where the equilibrium composition for a reversible non-ideal chemical system is identical to the corresponding composition for the ideal chemical system.
View Article and Find Full Text PDFAcc Chem Res
January 2025
School of Engineering, Westlake University, Hangzhou 310024, Zhejiang Province, China.
ConspectusCovalent triazine frameworks (CTFs) are a novel class of nitrogen-rich conjugated porous organic materials constructed by robust and functional triazine linkages, which possess unique structures and excellent physicochemical properties. They have demonstrated broad application prospects in gas/molecular adsorption and separation, catalysis, energy conversion and storage, etc. In particular, crystalline CTFs with well-defined periodic molecular network structures and regular pore channels can maximize the utilization of the features of CTFs and promote a deep understanding of the structure-property relationship.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Polymer Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.
Polyethers are versatile materials extensively used in advanced as well as everyday applications. The incorporation of primary amine functionality into polyethers is particularly attractive due to its well-established coupling chemistries. However, the inherent nucleophilicity of amine group poses a challenge in the anionic ring-opening polymerization (ROP) of epoxides and requires the use of robust protecting groups that can withstand the harsh conditions of ROP without triggering undesirable side reactions.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
Department of Chemistry, Indian Institute of Technology Bhilai, Durg, Chhattisgarh, 491002, India.
Utilization of reusable catalysts and reaction media has recently been an area of interest to devise a sustainable approach. Interestingly, photoinduced reversible deactivation radical polymerization (photoRDRP) of glycidyl methacrylate (GMA) is achieved with reusable and magnetically separable nano zero-valent Iron (nZVI). This resulted in well-defined poly(glycidyl methacrylate) (PGMA) (upto 22700 g mol) with a low dispersity (Đ ≤ 1.
View Article and Find Full Text PDFJ Cell Mol Med
January 2025
Department of Anesthesiology, Union Hospital, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, China.
Recently, RIT1 has been implicated in a range of neurological disorders; however, its precise function in glioma pathogenesis is not yet well-defined. This study employed quantitative reverse transcription PCR (qRT-PCR), Western blotting (WB), immunohistochemistry (IHC) and additional methodologies to assess RIT1 expression levels in glioma tissues. Furthermore, the study investigated its influence on glioma progression through a series of functional experiments.
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