We study the collision probability p of particles advected by open flows with chaotic advection. We show that p scales with the particle size (or, alternatively, reaction distance) δ as a power law whose coefficient is determined by the fractal dimensions of the invariant sets defined by the advection dynamics. We also argue that this same scaling also holds for the reaction rate of active particles in the low-density regime. These analytical results are compared to numerical simulations, and they are found to agree very well.
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http://dx.doi.org/10.1103/PhysRevLett.107.274501 | DOI Listing |
Herein, a novel magnetic resorcinol-formaldehyde-supported isatin-Schiff-base/Fe complex (FeO@RF-ISB/Fe) is prepared and characterized and its catalytic performance is investigated in the synthesis of pyrano[2,3-]pyrimidines. The FeO@RF-ISB nanomaterial was prepared through the chemical immobilization of (3-aminopropyl)trimethoxysilane over the FeO@RF composite, followed by treatment with isatin. The FeO@RF-ISB was then reacted with FeCl·6HO to afford the FeO@RF-ISB/Fe nanocatalyst.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Physics, University of Okara, Okara, 56300, Pakistan.
Sustainability and environmental protection are reshaping industries, including construction, where sustainability plays a crucial role in its influence on global resource consumption and waste management. The current study has developed a reusable cement material by photo-chemical surface modification of marble powder, achieved by reacting glycidyl methacrylate with carbonate functionality. This innovative modified marble powder boosts the reusability of construction materials, unlocking new possibilities for sustainable building practices.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Henan Key Laboratory of High Temperature Functional Ceramics, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
This study investigates the effect of the exsolution behavior of alumina-rich spinel on the formation and distribution of CA (CaAlO) in corundum castables bonded with calcium aluminate cement. In this study, alumina-rich spinel is substituted for tabular corundum in the same proportions and grain size. The matrices after curing were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS).
View Article and Find Full Text PDFJ Fluoresc
January 2025
Infectious Disease Department, Hangzhou First People's Hospital Tonglu Hospital, Hangzhou, Zhejiang, China.
This study synthesizes a novel three-dimensional (3D) porous coordination polymer (CP), {[Co(L)₀.₅(H₂O)]·NMP·H₂O} (1), via a solvothermal method in a mixed solvent of water and NMP (1-methyl-2-pyrrolidinone), reacting Co(II) ions with H₄L (1,4-bis(5,6-carboxybenzimidazolylmethyl)benzene). The CP exhibits unique fluorescence properties, emitting at 420 nm under UV light excitation at 350 nm, and serves as a carrier for Mesalazine (MSZ) in therapeutic applications.
View Article and Find Full Text PDFChem Res Toxicol
January 2025
Department of Environmental Sciences, University of California, Riverside, California 92521, United States.
E-cigarette emissions, which contain a variety of hazardous compounds, contribute significantly to indoor air pollution and raise concerns about secondhand exposure to vaping byproducts. Compared to fresh vape emissions, our understanding of chemically aged products in indoor environments remains incomplete. Terpenes are commonly used as flavoring agents in e-liquids, which have the ability to react with the dominant indoor oxidant ozone (O) to produce reactive oxygenated byproducts and result in new particle formation.
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