The first {Dy4} single-molecule magnet with a toroidal magnetic moment in the ground state.

Inorg Chem

MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China.

Published: February 2012

A toroidal magnetic moment in the absence of a conventional total magnetic moment was first observed in a novel tetranuclear dysprosium cluster with nonmagnetic ground state. The toroidal state is quite robust with respect to variations of the exchange parameters.

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http://dx.doi.org/10.1021/ic202650fDOI Listing

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