A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 1034
Function: getPubMedXML

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3152
Function: GetPubMedArticleOutput_2016

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(IV) nitride. | LitMetric

Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(IV) nitride.

Chem Commun (Camb)

Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Published: February 2012

(t-BuPOCOP)MoI(2) (1; t-BuPOCOP = C(6)H(3)-1,3-[OP(t-Bu)(2)](2)) has been synthesized from MoI(3)(THF)(3). Upon reduction of 1 with Na/Hg under dinitrogen molecular nitrogen is cleaved to form [(t-BuPOCOP)Mo(I)(N)](-). The origin of the N atom was confirmed using (15)N(2). Protonation of [(t-BuPOCOP)Mo(I)(N)](-) results in the formation of a neutral species in which it is proposed that the proton has added across the Mo-P bond.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c2cc17634cDOI Listing

Publication Analysis

Top Keywords

cleavage dinitrogen
4
dinitrogen yield
4
yield t-bupocopmolybdenumiv
4
t-bupocopmolybdenumiv nitride
4
nitride t-bupocopmoi2
4
t-bupocopmoi2 t-bupocop
4
t-bupocop c6h3-13-[opt-bu2]2
4
c6h3-13-[opt-bu2]2 synthesized
4
synthesized moi3thf3
4
moi3thf3 reduction
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!