In the title compound, C(17)H(19)NO(5), the cyclo-hexene ring is in a half-chair conformation and the isoxazole ring in an envelope conformation with the N atom as the flap. The C atoms in the 4- and 6-positions are of the same absolute configuration, whereas the C atom in the 5-position is of the opposite configuration, i.e. (4S*,5R*,6S*). The methyl fragment of the eth-oxy-carbonyl group at position 5 is disordered over two sets of sites in a 0.60:0.40 ratio. The crystal packing displays inter-molecular N-H⋯O and O-H⋯O hydrogen bonds.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247417PMC
http://dx.doi.org/10.1107/S1600536811042395DOI Listing

Publication Analysis

Top Keywords

rac-ethyl 6-hy-droxy-6-methyl-3-oxo-4-phenyl-134567-hexa-hydro-benzo[c][12]oxazole-5-carboxyl-ate
4
6-hy-droxy-6-methyl-3-oxo-4-phenyl-134567-hexa-hydro-benzo[c][12]oxazole-5-carboxyl-ate title
4
title compound
4
compound c17h19no5
4
c17h19no5 cyclo-hexene
4
cyclo-hexene ring
4
ring half-chair
4
half-chair conformation
4
conformation isoxazole
4
isoxazole ring
4

Similar Publications

In the title compound, C(17)H(19)NO(5), the cyclo-hexene ring is in a half-chair conformation and the isoxazole ring in an envelope conformation with the N atom as the flap. The C atoms in the 4- and 6-positions are of the same absolute configuration, whereas the C atom in the 5-position is of the opposite configuration, i.e.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!