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1,1'-{2,2'-[1,4-Phenyl-enebis(methyl-ene)]bis-(-oxy)bis-(2,1-phenyl-ene)}diethanone. | LitMetric

1,1'-{2,2'-[1,4-Phenyl-enebis(methyl-ene)]bis-(-oxy)bis-(2,1-phenyl-ene)}diethanone.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Published: November 2011

The asymmetric unit of the title compound, C(24)H(22)O(4), contains one half-mol-ecule, the other half being generated by a crystallographic center of inversion. The central benzene ring makes a dihedral angle of 72.49 (5)° with the terminal benzene ring. In the crystal, adjacent mol-ecules are linked through C-H⋯O inter-actions, forming a sheet structure parallel to the bc plane. The sheets are stacked along the a axis via π-π inter-actions formed between the terminal benzene rings [centroid-centroid separation = 3.7276 (6) Å].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247415PMC
http://dx.doi.org/10.1107/S1600536811042528DOI Listing

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