Benzyl (E)-3-(4-meth-oxy-benzyl-idene)dithio-carbazate.

Acta Crystallogr Sect E Struct Rep Online

Published: November 2011

The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio-carbazate and 4-meth-oxy-benzaldehyde. In the mol-ecule, the meth-oxy-phenyl ring and dithio-carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio-carbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the meth-oxy-phenyl and phenyl rings. Inter-molecular N-H⋯S hydrogen bonds and weak C-H⋯π inter-actions are observed in the crystal structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247410PMC
http://dx.doi.org/10.1107/S1600536811042140DOI Listing

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