The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], con-tains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph(2)PP(O)Ph(2)]. Both Fe-atom geometries could be described as grossly distorted octa-hedral and the Ph(2)PP(O)Ph(2) ligand lies trans to the Fe⋯Fe link.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246973 | PMC |
| http://dx.doi.org/10.1107/S1600536811042139 | DOI Listing |
Publication Analysis
Top Keywords
carbonyl ligands
8
dinuclear title
4
title compound
4
compound [fe2c2h4s2c24h20op2co5]
4
[fe2c2h4s2c24h20op2co5] μ-sch2ch2s-μfe2co5[ph2ppoph2]
4
μ-sch2ch2s-μfe2co5[ph2ppoph2] con-tains
4
con-tains butterfly-shaped
4
butterfly-shaped fe2s2
4
fe2s2 core
4
core fe⋯fe
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!