catena-Poly[[bis-(μ-2-formyl-6-meth-oxy-phenolato)copper(II)sodium]-μ-nitrato].

Acta Crystallogr Sect E Struct Rep Online

School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

Published: November 2011

In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu(II) and Na ions, forming a layered arrangement extending parallel to (001).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246950PMC
http://dx.doi.org/10.1107/S1600536811040025DOI Listing

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