Polycyclic aromatic hydrocarbons (PAHs) were measured in the PM(10) particle fraction collected at two different measuring sites in Zagreb, Croatia. In summer, concentrations of all PAHs at both sites were low. In winter, mass concentrations of all PAHs measured at southern site were much higher than those at north. Contents of all PAHs in the PM(10) particle fraction were much lower in summer than that in the winter period. For example, average content of BaP in PM(10) in summer was 2.26 ng/mg at site A and 4.17 ng/mg at site B, while in winter it was 34.72 and 46.69 ng/mg, respectively.
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http://dx.doi.org/10.1007/s00128-011-0516-4 | DOI Listing |
ACS Earth Space Chem
January 2025
School of Chemistry, Norwich Research Park, University of East Anglia, Norwich NR4 7TJ, U.K.
2-Cyanoindene is one of the few specific aromatic or polycyclic aromatic hydrocarbon (PAH) molecules positively identified in Taurus molecular cloud-1 (TMC-1), a cold, dense molecular cloud that is considered the nearest star-forming region to Earth. We report cryogenic mid-infrared (550-3200 cm) and visible (16,500-20,000 cm, over the ← electronic transition) spectra of 2-cyanoindene radical cations (2CNI), measured using messenger tagging (He and Ne) photodissociation spectroscopy. The infrared spectra reveal the prominence of anharmonic couplings, particularly over the fingerprint region.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, Indian Institute of Technology, Guwahati 781039, India.
Charge transfer (CT) states in polycyclic aromatic hydrocarbons play crucial roles in determining their electronic properties and their potential applications in organic electronics. In this work, we investigate the nature of the excited states in monomers and π-stacked dimers of azulene-fused naphthalene and anthracene systems, focusing on the interplay between structure and excited-state properties. Four different isomers for azulene-fused naphthalene (, , , and ) and anthracene (, , , and ) are considered.
View Article and Find Full Text PDFEnviron Pollut
January 2025
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China.
Natural attenuation represents a significant ecosystem function for mitigating the quantity and toxicity of polycyclic aromatic hydrocarbons (PAHs) through both abiotic and biotic dissipation processes. This study systematically investigated abiotic and biotic dissipation of phenanthrene (Phe) and benzo[a]pyrene (BaP) in four soils over 360 days, using CSIA to quantitatively analyze δ³C changes and demonstrate biodegradation. The results indicated that extractable Phe was primarily attenuated via biodegradation (65% - 81%), as revealed by CSIA, with the δ³C changes ranging from 2.
View Article and Find Full Text PDFOrg Lett
January 2025
Department of Materials Science, State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Molecular Materials and Devices, Fudan University, Shanghai 200433, China.
Two series of polycyclic aromatic hydrocarbon isomers ( and , and and ) were designed and synthesized by isomerically fusing phenanthrene with thiophene and thieno[3,2-]thiophene, respectively. All of the new target molecules were confirmed by single-crystal X-ray analysis, and it was found that the solid-state packing can be effectively modulated through a combination of π-extended and isomeric fused strategies. Meanwhile, compared with thiophene ring-terminated isomers and , both having a V-shaped geometry and showing no obvious self-assembly behavior, π-extended unit thieno[3,2-]thiophene-terminated isomer displays a V-shaped structure with moderate self-assembly properties and isomer exhibits a C-shaped configuration with further enhanced self-assembly properties.
View Article and Find Full Text PDFAnal Methods
January 2025
Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran.
In the present research, an attempt has been made to develop a new thin film microextraction method for the extraction of several polycyclic aromatic hydrocarbons from aqueous samples collected from different industrial units prior to their analysis by gas chromatography combined with a flame ionization detector. In this approach, a thin iron mesh was modified by the formation of iron(II) oxinate on its surface and used for the extraction of analytes without an additional sorbent. For this purpose, first, the mesh was immersed in a sulfuric acid solution and then transferred into an 8-hydroxy quinoline (oxine) solution dissolved in ammonia solution.
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