In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H⋯O and N-H⋯O hydrogen bonds. C-H⋯π inter-actions are also observed between the cation and the anion.
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http://dx.doi.org/10.1107/S1600536811048860 | DOI Listing |
IUCrdata
August 2024
Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.
Anal Sci
April 2024
Chemistry Department, Faculty of Science, Sohag University, Sohag, 82524, Egypt.
Among the toxic heavy metals, Ni(II) can cause a variety of side effects on human health, such as allergy, cardiovascular and kidney diseases, lung fibrosis, lung, and nasal cancer. It is therefore critical from a public health and environmental perspective to determine and monitor Ni(II) ions in drinking water, foods, and environmental samples. In this study, a novel selective chemosensor (4-[{[4-(3-Chlorophenyl)-1,3-Thiazol-2-yl]Hydrazono}Methyl]phenyl4-methylBenzene Sulfonate (CTHMBS) was developed for the colorimetric detection of Ni(II) in aqueous medium.
View Article and Find Full Text PDFBiomed Chromatogr
January 2024
Department of Chemistry, School of Science, GITAM Deemed to be University, Hyderabad, Telangana, India.
This study performed the simultaneous quantification of assay and two alkyl sulfonate (tosylate) analogs of empagliflozin (EGZ), specifically methyl 4-methyl benzene sulfonate (MMBS) and ethyl 4-methyl benzene sulfonate (EMBS) in EGZ, and its finished dosage form using an accurate and sensitive ultra-performance liquid chromatography-mass spectrometry method. The separation was achieved on a Waters Acquity BEH Shield RP18 (100 × 2.1 mm, 1.
View Article and Find Full Text PDFIUCrdata
May 2022
School of Math and Science, Walsh University, 2020 East Maple Street, North Canton, OH 44720, USA.
The structure of the title salt (systematic name: oxodiphenyl-λ-iodanylium 4-methyl-benzene-sulfonate dihydrate), CHIO·CHOS·2HO, at 150 K, has monoclinic (2/) symmetry. The mol-ecular structure features an angular (phenyl-iodos-yl)benzene cation, the geometry of which was hitherto undescribed in the literature: in the cation, both I-C bonds are approximately normal to the I=O bond, forming a C-I-C angle of 95.36 (4)°.
View Article and Find Full Text PDFIUCrdata
February 2020
School of Chemical Sciences, Goa University PO, Goa 403206, India.
In the extended structure of the title mol-ecular salt, CHN ·CHOS, the cations and anions are linked by N-H⋯O hydrogen bonds to generate [010] chains.
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