In the title compound, C(9)H(8)N(2), a mirror plane lies perpendicular to the phenyl and imidazole rings and passes through the bridging C-C bond, so that the imidazole ring is disordered over two sites about the mirror plane with the equal site occupancy; the asymmetric unit contains one half-mol-ecule. In the crystal, adjacent mol-ecules are linked via N-H⋯N hydrogen bonds.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238905 | PMC |
| http://dx.doi.org/10.1107/S160053681104699X | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Emergent superconductivity driven by Van Hove singularity in a Janus MoPS monolayer.
Phys Chem Chem Phys
January 2025
School of Physics and Electronics, Hunan University, Changsha 410082, China.
Two-dimensional (2D) Janus structures with the breaking of out-of-plane mirror symmetry can induce many interesting physical phenomena, and have attracted widespread attention. Herein, we propose a MoPS monolayer with mirror asymmetry, identified by first-principles structural search calculations, which demonstrates high thermodynamic and dynamic stability. Our findings reveal that Mo 4d-orbitals dominate the metallicity, significantly enhancing the density of states near the Fermi level due to Van Hove singularities (VHSs), leading to the existence of phonon-mediated superconductivity.
View Article and Find Full Text PDFExtreme Optical Chirality from Plasmonic Nanocrystals on a Mirror.
Nano Lett
January 2025
NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, University of Cambridge, Cambridge CB3 0HE, United Kingdom.
Metal nanocrystals synthesized in achiral environments usually exhibit no chiroptical effects. However, by placing nominally achiral nanocrystals 1.3 nm above gold films, we find giant chiroptical effects, reaching anisotropy factors as high as ≈ 0.
View Article and Find Full Text PDFFrequency-domain thermoreflectance with beam offset without the spot distortion for accurate thermal conductivity measurement of anisotropic materials.
Rev Sci Instrum
January 2025
Department of Micro Engineering, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura C3, Nishikyo-ku, Kyoto 615-8540, Japan.
The measurement of thermal conductivities of anisotropic materials and atomically thin films is pivotal for the thermal design of next-generation electronic devices. Frequency-domain thermoreflectance (FDTR) is a pump-probe technique that is known for its accurate and straightforward approach to determining thermal conductivity and stands out as one of the most effective methodologies. Existing research has focused on advancing a measurement system that incorporates beam-offset FDTR.
View Article and Find Full Text PDFSynthesis, crystal structure and thermal properties of poly[di-μ-bromido-(μ-2,5-di-methyl-pyrazine)cadmium(II)].
Acta Crystallogr E Crystallogr Commun
January 2025
Institut für Anorganische Chemie, Universität Kiel, Max-Eyth.-Str. 2, 24118 Kiel, Germany.
The title compound, [CdBr(CHN)] , was prepared by the reaction of cadmium bromide with 2,5-di-methyl-pyrazine in water. Its asymmetric unit consists of one Cd cation and one 2,5-di-methyl-pyrazine ligand that are located on a crystallographic mirror plane as well as one bromide anion that occupies a general position. The Cd cations are sixfold coordinated by four bromide anions and two 2,5-di-methyl-pyrazine ligands within slightly distorted -CdBrN octa-hedra.
View Article and Find Full Text PDFOn-machine separation and compensation of target mirror's surface shape errors in multidimensional interferometric measurement system.
Rev Sci Instrum
January 2025
School of Instrument Science and Opto-Electronic Engineering, Hefei University of Technology, Hefei 230009, China.
In multi-dimensional nanopositioning and nanomeasuring devices, interference measurement is widely used. The three-dimensional (3D) target mirror serves as the spatial reference plane to achieve multidimensional interference measurements. However, the surface shape errors of the target mirror are superimposed on the geometric dimensions of the measured workpiece, which limits the system's overall measurement accuracy.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!