The mol-ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl-idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by weak C-H⋯O inter-actions into chains along the c axis which are stacked along the b axis by aromatic π-π inter-actions with a centroid-centroid distance of 3.5927 (10) Å.
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http://dx.doi.org/10.1107/S1600536811045417 | DOI Listing |
Biochemistry
January 2025
Division of Food Science and Biotechnology, Graduate School of Agriculture, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
CYP105A1 exhibits monooxygenase activity to a wide variety of structurally different substrates with regio- and stereospecificity, making its application range broad. Our previous studies have shown that CYP105A1 wild type and its variants metabolize 12 types of nonsteroidal anti-inflammatory drugs (NSAIDs). In particular, the R84A variant exhibited a high activity against many NSAIDs.
View Article and Find Full Text PDFEnviron Sci Technol
December 2024
Yunnan Provincial Key Lab of Soil Carbon Sequestration and Pollution Control, Faculty of Environmental Science & Engineering, Kunming University of Science & Technology, Kunming 650500, Yunnan China.
Polycyclic aromatic hydrocarbons (PAHs) are widespread contaminants that can accumulate in microorganisms, posing significant ecological risks. While previous studies primarily focused on PAH concentrations, the impacts of PAH self-clustering have been largely overlooked, which will lead to inaccurate assessments of their ecological risks. This study evaluates the toxic effects of four prevalent PAH clusters on microbes with an emphasis on comparing the cluster sizes.
View Article and Find Full Text PDFJ Environ Manage
December 2024
Environmental Engineering Division, Department of Civil Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu, 600036, India. Electronic address:
The release of toxic chemical dyes from the industrial effluent poses huge challenges for the environmental engineers to treat it. Azo dyes encompass the huge part of textile discharges which are difficult to degrade due to their complex chemical aromatic structures and due to the presence of strong bonds (-N=N-). Thus, the removal of a carcinogenic azo dye (i.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
University of Copenhagen, Department of Chemistry, Universitetsparken 5, DK-2100, Copenhagen, DENMARK.
The introduction of 4,5-dihydroazuleno[2,1,8-ija]azulene as a central core between two 1,4-dithiafulvene (DTF) units provides a novel class of extended tetrathiafulvalene (TTF) electron donors. Herein we present the synthesis of such compounds with the azulenoazulene further expanded by annulation to benzene, naphthalene, or thiophene rings. Moreover, unsymmetrical donor-acceptor chromophores with one DTF and one carbonyl at the central core are presented.
View Article and Find Full Text PDFChemistry
December 2024
Hebei University, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education, Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Materials Science,, CHINA.
Flexible film in display requires multi-functional integration, such as stretchability, flexibility, abrasion resistance, transparency, and shape memory. In this paper, a reasonable design strategy of flexible polyacrylate (PA) film with high transparency, shape memory, excellent abrasion resistance and foldability is presented. The PA films are prepared by free radical polymerization of vinyl-terminated polyurethane (PU) prepolymer as a cross-linking agent and acrylate monomers in ultraviolet (UV) light.
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