AI Article Synopsis
- The compound {[Co(NCS)(2)(C(6)H(4)N(2))(4)]·2C(4)H(8)O(2)} features cobalt (Co(II)) ions that are octahedrally coordinated by two thio-cyanate ions and four 3-cyano-pyridine ligands.
- The crystal unit includes one Co(II) ion, a thio-cyanate anion, a dioxane molecule, and a 3-cyano-pyridine ligand; the Co(II) ion sits on a site with mirror symmetry.
- The structure forms distinct complexes and also contains disordered 1,4
Article Abstract
In the crystal structure of the title compound, {[Co(NCS)(2)(C(6)H(4)N(2))(4)]·2C(4)H(8)O(2)}, the Co(II) cations are octa-hedrally coordinated by two terminal N-bonded thio-cyanate anions and four N-bonded 3-cyano-pyridine ligands. The asymmetric unit consists of one Co(II) cation, which is located on a special position with site symmetry 2/m, one thio-cyanate anion and one dioxane mol-ecule, located on a crystallographic mirror plane, as well as one 3-cyano-pyridine ligand in a general position. The crystal structure consists of discrete complexes of [Co(NCS)(2)(3-cyano-pyridine)(4)], as well as two non-coordinating 1,4-dioxane solvent mol-ecules which are disordered due to symmetry.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238779 | PMC |
| http://dx.doi.org/10.1107/S1600536811051087 | DOI Listing |
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