Tetra-μ-acetato-κO:O'-bis-{[2,2-dimeth-yl-N-(pyridin-2-yl)propanamide-κN]copper(II)}(Cu-Cu).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Louisville, Louisville, KY 40292, USA.

Published: December 2011

The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octa-hedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu-Cu bond. The amide H atom forms intra-molecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak inter-molecular pyridine-amide C-H⋯O inter-actions are also present.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238774PMC
http://dx.doi.org/10.1107/S1600536811050124DOI Listing

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