Poly[(aqua-calcium)-μ(4)-pyrazine-2,3-di-carboxyl-ato].

Acta Crystallogr Sect E Struct Rep Online

Published: December 2011

The polymeric title compound, [Ca(C(6)H(2)N(2)O(4))(H(2)O)](n), was synthesized from pyrazine-2,3-dicarb-oxy-lic acid and calcium dichloride under hydro-thermal conditions. The Ca(2+) cation is seven-coordinated by five O atoms and one N atom of four pyrazine-2,3-dicarboxyl-ate anions, and one water mol-ecule. The complete deprotonated pyrazine-2,3-dicarboxyl-ate anion adopts a μ(4)-coordination mode, resulting in the formation of a three-dimensional structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238750PMC
http://dx.doi.org/10.1107/S1600536811050276DOI Listing

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