catena-Poly[[trimethyl-tin(IV)]-μ-5-methyl-thio-phene-2-carboxyl-ato-κO:O'].

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Published: December 2011

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238733PMC
http://dx.doi.org/10.1107/S1600536811049713DOI Listing

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