AI Article Synopsis
- The compound consists of two CdCl₄ units coordinated by a Cd(II) ion that is symmetrically arranged with four chloride ions at specific bond lengths.
- A chain structure is formed along the c-axis due to multiple hydrogen bonding interactions, including C-H⋯N connections between units.
- Additional weak interactions, such as π-π interactions between pyrimidine rings and N-H bonds interacting with chloride and oxygen, are also present in the structure.
Article Abstract
In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C-H⋯N hydrogen-bonding inter-actions and a weak π-π inter-action is observed between the pyrimidine rings of two adjacent parallel chains [centroid-centroid distance = 3.722 (2) Å]. N-H⋯Cl, CN-H⋯Cl and N-H⋯O interactions also occur.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238717 | PMC |
| http://dx.doi.org/10.1107/S1600536811045995 | DOI Listing |
Publication Analysis
Top Keywords
bis{3-[2-methyl-sulfon-ylpyrimidin-4-yl]pyridinium} tetra-chloridocadmium
4
tetra-chloridocadmium title
4
title compound
4
compound c10h10n3o2s2[cdcl4]
4
c10h10n3o2s2[cdcl4] cdii
4
cdii ion
4
ion lies
4
lies twofold
4
twofold axis
4
axis coordinated
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!