Bis{1,2-bis-[bis-(3-meth-oxy-prop-yl)phosphan-yl]ethane-κP,P'}dichlorido-osmium(II).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, 1253 University of Oregon, Eugene, Oregon 97403-1253, USA.

Published: December 2011

In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the meth-oxy side chains of the ligand is disordered over two orientations in a 0.700 (6):0.300 (6) ratio.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238713PMC
http://dx.doi.org/10.1107/S1600536811048926DOI Listing

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