AI Article Synopsis
- The studied complex contains a zinc ion coordinated to two bidentate 2,2'-bipyridine ligands and two dimethyl sulfoxide (DMSO) molecules, forming a distorted octahedral structure.
- The S atom and methyl groups of one DMSO molecule are found to be disordered, existing in nearly equal proportions.
- Crystal stabilization occurs through C-H⋯O hydrogen bonding between DMSO solvent molecules and tetra-phenyl-borate anions.
Article Abstract
In the mononuclear title complex, [Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)](C(24)H(20)B)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2'-bipyridine mol-ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol-ecules in a distorted octa-hedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide mol-ecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C-H⋯O hydrogen bonds between the dimethyl sulfoxide solvent mol-ecules and tetra-phenyl-borate anions.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238690 | PMC |
| http://dx.doi.org/10.1107/S1600536811048082 | DOI Listing |
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