Hexaaqua-cobalt(II) bis-(5-acetyl-2-hy-droxy-benzoate) dihydrate.

Acta Crystallogr Sect E Struct Rep Online

Published: December 2011

In the title compound, [Co(H(2)O)(6)](C(9)H(7)O(4))(2)·2H(2)O, the Co(2+) cation lies on a twofold rotation axis and is coordinated by six water mol-ecules in a distorted octa-hedral geometry. In the 5-acetyl-2-hy-droxy-benzoate anion, the hy-droxy group links with the carboxyl-ate group via an intra-molecular O-H⋯O hydrogen bond and the acetyl group is twisted to the benzene ring at a dihedral angle of 16.99 (12)°. In the crystal structure, the cations, anions and water mol-ecules are linked by extensive O-H⋯O hydrogen bonding.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238644PMC
http://dx.doi.org/10.1107/S1600536811046678DOI Listing

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