AI Article Synopsis
- Researchers are exploring "smart materials" that integrate supramolecular interactions with temperature-sensitive polymers.
- Poly(N-isopropylacrylamide)-block-polystyrene copolymers are used to create micelles in water, which have terpyridine ligands attached.
- The study investigates how temperature changes and the presence of Zn(II) ions affect the micelles' ability to self-assemble.
Article Abstract
An attractive concept for designing "smart materials" is the combination of supramolecular interactions with thermoresponsive polymers. Here, this concept is illustrated by preparing aqueous micelles from poly(N-isopropylacrylamide)-block-polystyrene copolymers functionalized at the extremity of their poly(N-isopropylacrylamide) coronal chains by terpyridine ligands. The effect of temperature and of the addition of Zn(II) ions on the self-assembling properties is then studied.
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| http://dx.doi.org/10.1002/marc.201100640 | DOI Listing |
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