Application of hydrostatic pressure under adiabatic conditions causes a change in temperature in any substance. This effect is known as the barocaloric effect and the vast majority of materials heat up when adiabatically squeezed, and they cool down when pressure is released (conventional barocaloric effect). There are, however, materials exhibiting an inverse barocaloric effect: they cool when pressure is applied, and they warm when it is released. Materials exhibiting the inverse barocaloric effect are rather uncommon. Here we report an inverse barocaloric effect in the intermetallic compound La-Fe-Co-Si, which is one of the most promising candidates for magnetic refrigeration through its giant magnetocaloric effect. We have found that application of a pressure of only 1 kbar causes a temperature change of about 1.5 K. This value is larger than the magnetocaloric effect in this compound for magnetic fields that are available with permanent magnets.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1038/ncomms1606 | DOI Listing |
Sci Adv
February 2023
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, Liaoning 110016, China.
To harvest and reuse low-temperature waste heat, we propose and realize an emergent concept-barocaloric thermal batteries based on the large inverse barocaloric effect of ammonium thiocyanate (NHSCN). Thermal charging is initialized upon pressurization through an order-to-disorder phase transition, and the discharging of 43 J g takes place at depressurization, which is 11 times more than the input mechanical energy. The thermodynamic equilibrium nature of the pressure-restrained heat-carrying phase guarantees stable long-duration storage.
View Article and Find Full Text PDFMolecules
October 2020
Coordenação de Ciências Naturais, Universidade Federal do Maranhão, Campus do Bacabal, São Luís 65700-000, Brazil.
Temperature-dependent Raman scattering and differential scanning calorimetry were applied to the study of the hybrid organic-inorganic azide-perovskite [(CH)N][Cd(N)], a compound with multiple structural phase transitions as a function of temperature. A significant entropy variation was observed associated to such phase transitions, |∆S| ~ 62.09 J·kg K, together with both a positive high barocaloric (BC) coefficient |δT/δP| ~ 12.
View Article and Find Full Text PDFAdv Mater
September 2019
Department of Materials Science, University of Cambridge, Cambridge, CB3 0FS, UK.
Hydrostatic pressure represents an inexpensive and practical method of driving caloric effects in brittle magnetocaloric materials, which display first-order magnetostructural phase transitions whose large latent heats are traditionally accessed using applied magnetic fields. Here, moderate changes of hydrostatic pressure are used to drive giant and reversible inverse barocaloric effects near room temperature in the notoriously brittle magnetocaloric material MnCoGeB . The barocaloric effects compare favorably with those observed in barocaloric materials that are magnetic.
View Article and Find Full Text PDFNat Commun
November 2017
Facultat de Física, Departament de Física de la Matèria Condensada, Universitat de Barcelona, Martí i Franquès, 1, 08028, Barcelona, Catalonia, Spain.
Current interest in barocaloric effects has been stimulated by the discovery that these pressure-driven thermal changes can be giant near ferroic phase transitions in materials that display magnetic or electrical order. Here we demonstrate giant inverse barocaloric effects in the solid electrolyte AgI, near its superionic phase transition at ~420 K. Over a wide range of temperatures, hydrostatic pressure changes of 2.
View Article and Find Full Text PDFNat Commun
November 2015
Facultat de Física, Departament d'Estructura i Constituents de la Matèria, Universitat de Barcelona, Martí i Franquès 1, Barcelona, 08028 Catalonia, Spain.
Caloric effects are currently under intense study due to the prospect of environment-friendly cooling applications. Most of the research is centred on large magnetocaloric effects and large electrocaloric effects, but the former require large magnetic fields that are challenging to generate economically and the latter require large electric fields that can only be applied without breakdown in thin samples. Here we use small changes in hydrostatic pressure to drive giant inverse barocaloric effects near the ferrielectric phase transition in ammonium sulphate.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!