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Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones. | LitMetric
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Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones.

Nevin Gürbüz Emine Özge Özcan İsmail Özdemir Bekir Çetinkaya Onur Şahin Orhan Büyükgüngör

Dalton Trans

İnönü University, Faculty of Science, Department of Chemistry, 44280, Malatya, Turkey.

Published: February 2012

The reaction of [RuCl(2)(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene)Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction.

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http://dx.doi.org/10.1039/c1dt11203aDOI Listing

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