Surface-aligning field in smectic liquid-crystal films.

Two modified mean-field J(1)-J(2) models are studied to explain the surface reduction of twisting power in the helical smectic-C*(α) phase in free-standing liquid crystal films. Profiles of the surface interlayer interaction are calculated from the experimental results. The calculations reveal the existence of a strong surface field and indicate that the surface field is the reason for the observed reduced twisting power near the surface region. Our results provide a quantitative study of the interlayer interactions through surface effects in smectic liquid crystals.